2018
DOI: 10.1016/j.marpetgeo.2018.04.010
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Redox conditions and authigenic mineralization related to cold seeps in central Guaymas Basin, Gulf of California

Abstract: Authigenic carbonate crusts, surface muds and bivalve shell fragments have been recovered from inactive and active recently discovered cold seep sites in central Guaymas Basin.. In this study, for first time, redox conditions and fluid sources involved in mineral precipitation were investigated by analyzing the mineralogy and textures of surface samples, along with skeletal contents, and C, O and S isotopes variations. The δ 13 C values of aragonitic bivalve shells and non-skeletal carbonate

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Cited by 25 publications
(17 citation statements)
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References 95 publications
(140 reference statements)
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“…1 mile further west outside Ringvent, and also not in any other core collected during the 2014 Expedition (details in Methods: Field surveys). XRD examination (Supplemental Data 2) shows that these carbonates consist of magnesian calcite, compositionally similar to cold seep carbonates reported previously for Guaymas Basin 22 . These localized carbonate concretions exhibit light δ 13 C values from −37 to −41‰, whereas smaller, visually inconspicuous carbonate grains and particles in sediment surrounding these nodules show slightly heavier δ 13 C values from −37 to −30‰ (Figs 4 and 5A, and Supplementary Data 3).…”
Section: Resultssupporting
confidence: 80%
See 1 more Smart Citation
“…1 mile further west outside Ringvent, and also not in any other core collected during the 2014 Expedition (details in Methods: Field surveys). XRD examination (Supplemental Data 2) shows that these carbonates consist of magnesian calcite, compositionally similar to cold seep carbonates reported previously for Guaymas Basin 22 . These localized carbonate concretions exhibit light δ 13 C values from −37 to −41‰, whereas smaller, visually inconspicuous carbonate grains and particles in sediment surrounding these nodules show slightly heavier δ 13 C values from −37 to −30‰ (Figs 4 and 5A, and Supplementary Data 3).…”
Section: Resultssupporting
confidence: 80%
“…Carbonate nodules and grains in core P11 are significantly lighter than organic carbon in the same core, between −20.5 and −22‰ (see Methods), and previously analyzed sedimentary organic carbon and chemosynthetic microbial biomass (−21.6 and −22.1‰, respectively) in Guaymas Basin 23 , indicative of contributions from methane-derived carbon sources. In their δ 13 C isotopic composition, the nodules resemble independently collected carbonates (−36.5‰) from surface mud of Ringvent 22 , and differ from cold seep carbonates in Guaymas Basin (−46.6 and −44.7‰ 4 ; −45.2 and −47.6‰ 21 ). In contrast, sedimentary carbonates in core P11 above and below the nodules have moderate 13 C depletion ranging from −15 to 0‰ (Figs 4 and 5A), and approach δ 13 C-DIC values of seawater (−0.6‰) in Guaymas Basin 23 .…”
Section: Resultsmentioning
confidence: 86%
“…The gravity coring results allowed a preliminary geochemical and microbial characterization of the proposed ridge flank drill sites. The 2015 Sonne cruise collected numerous sediment cores and seafloor grab samples from Guaymas Basin and the adjacent Sonora Margin (Núñez-Useche et al, 2018;Geilert et al, 2018). The major discovery of this cruise was an actively venting hydrothermal mound at the northern Guaymas graben, located on the edge of the eastern ridge flanks and supplied with hot and gas-rich hydrothermal fluids from the spreading center through axial-parallel fault lines (Berndt et al, 2016).…”
Section: Site Surveys and Seismic Studiesmentioning
confidence: 99%
“…Several additional reactions such as organoclastic sulfate reduction (OSR) [7], authigenic precipitation of certain metallic elements [8], or formation and decomposition of gas hydrate [9] may also result in abnormal phenomena in the surrounding seawater, sediments, and ecosystems.…”
Section: Introductionmentioning
confidence: 99%