Redox poteftials of the aquo, cyano and EDTA complexes of some transition metal ions by CNDO calculations

Hard-to-detect CoIII/CoII reduction in a hexacyanocobaltate

“…where is the free energy of the reduction process; z is the number of electrons transferred (a value of -4.34 eV refers to the free energy of the reaction 13 H + (aq) ® 1/2H 2(aq) ). The reaction free energy was estimated as difference in the total energies of complexes including the solvation contributions.…”