Redox properties of titanocene-pyrrole derivative and its electropolymerization

Solution and solid state properties of Fe(III) complexes bearing N-ethyl-N-(2-aminoethyl)salicylaldiminate ligands

“…All experiments were performed in dry acetonitrile solutions (1 mM) and tetrabutylammonium tetrafluoroborate (NBu 4 BF 4 , 0.1 M). For complexes 1-6, ferrocene (E 1/2 = 0.420 V vs. SCE) [43] was used as internal standard.…”

Study of ferrocene derivatives Fe(C5H4X)(C5H5−n Y n ) by cyclic voltammetry and matrix-activated laser desorption/ionization time-of-flight mass spectrometry

“…The reference electrode was a silver wire placed in a solution of silver nitrate (0.01 M) and Bu 4 NPF 6 (0.2 M) in acetonitrile. 24 The values of detected oxidation and reduction potentials for the studied compounds rela tively to the chosen reference electrode and the ratio be tween the oxidation and reduction currents that charac terize the reversibility of the overall electrochemical pro cess are presented in Table 1. An analysis of the obtained values for oxidation potentials makes it possible to quanti tatively evaluate the electron donor ability of the substitu ents in the ferrocene derivatives.…”

Mechanisms of Electropolymerization and Redox Activity: Fundamental Aspects

“…The value of the (maximum) oxidation degree, α redox , depends on numerous factors, first of all on the monomer and the solvent. It is often estimated as about 0.2-0.3 for PPy and PTh and their derivatives, while it is about 0.5 for PAni or 0.6 for PEDOT [5,25,27,53,54]. In rare cases, a much higher charging degree was achieved, close to one electronic charge per monomer unit [55,56], which represents probably a ''natural limit'' for the oxidation level to be reached by electrochemical means.…”