Reducion of Oxygen to Superoxide Anion in Aprotic Solvents.

Maricle, D. L.; Hodgson, William G.

doi:10.1021/ac60231a027

Cited by 238 publications

(112 citation statements)

References 16 publications

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“…Bare lithium rapidly reacts with DMF; therefore, our Li-Air cells employed PLEs with LATP membranes. Electrochemical oxygen reduction in electrolytes based on DMF and tetraalkylammonium salts has been the subject of extensive research [21][22][23], and DMF was expected to be stable towards the products of oxygen reduction in Li-Air cells. Recently reported theoretical calculations of solvent reactivity [24] also confirm high stability of DMF against nucleophilic attack by superoxide.…”

Section: Resultsmentioning

confidence: 99%

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Visco

Nimon

Petrov

et al. 2014

J Solid State Electrochem

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The extremely high theoretical energy density of the lithium-oxygen couple makes it very attractive for nextgeneration battery development. However, there are a number of challenging technical hurdles that must be addressed for LiAir batteries to become a commercial reality. In this article, we demonstrate how the invention of water-stable, solid electrolyte-protected lithium electrodes solves many of these issues and paves the way for the development of aqueous and nonaqueous Li-Air batteries with unprecedented energy densities. We also show data for fully packaged Li-Air cells that achieve more than 800 Wh/kg.

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Section: Resultsmentioning

confidence: 99%

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Visco

Nimon

Petrov

et al. 2014

J Solid State Electrochem

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“…The kinetics of O 2 reduction in the presence of strongly coordinating Li + are sluggish (Supporting Information, Figure S1), and its elementary steps are not well understood. O 2 reduction proceeds first by the formation of superoxide (O 2 À ) [9,10] and then lithium superoxide (Li…”

mentioning

confidence: 99%

Experimental and Computational Analysis of the Solvent‐Dependent O₂/Li⁺‐O₂⁻ Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium–Oxygen Batteries

et al. 2016

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“…The fundamental reaction mechanism for both aqueous and hybrid electrolytes are similar. The fundamental reaction mechanisms for the aqueous electrolytes are as follows, (5) (in acidic electrolyte) (6) (in alkaline electrolyte)…”

Section: )mentioning

confidence: 99%

Lithium Air Battery: Alternate Energy Resource for the Future

Zahoor¹,

Christy²,

Hwang³

et al. 2012

Journal of Electrochemical Science and Technology

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:Increasing demand of energy, the depletion of fossil fuel reserves, energy security and the climate change have forced us to look upon alternate energy resources. For today's electric vehicles that run on lithium-ion batteries, one of the biggest downsides is the limited range between recharging. Over the past several years, researchers have been working on lithium-air battery. These batteries could significantly increase the range of electric vehicles due to their high energy density, which could theoretically be equal to the energy density of gasoline. Li-air batteries are potentially viable ultrahigh energy density chemical power sources, which could potentially offer specific energies up to 3000 Whkg −1 being rechargeable. This paper provides a review on Lithium air battery as alternate energy resource for the future.

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Reducion of Oxygen to Superoxide Anion in Aprotic Solvents.

Cited by 238 publications

References 16 publications

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Experimental and Computational Analysis of the Solvent‐Dependent O₂/Li⁺‐O₂⁻ Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium–Oxygen Batteries

Lithium Air Battery: Alternate Energy Resource for the Future

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Reducion of Oxygen to Superoxide Anion in Aprotic Solvents.

Cited by 238 publications

References 16 publications

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Aqueous and nonaqueous lithium-air batteries enabled by water-stable lithium metal electrodes

Experimental and Computational Analysis of the Solvent‐Dependent O2/Li+‐O2− Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium–Oxygen Batteries

Lithium Air Battery: Alternate Energy Resource for the Future

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Experimental and Computational Analysis of the Solvent‐Dependent O₂/Li⁺‐O₂⁻ Redox Couple: Standard Potentials, Coupling Strength, and Implications for Lithium–Oxygen Batteries