1975
DOI: 10.1016/s0022-328x(00)86954-5
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Reduction of carbonyl compounds via hydrosilylation

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Cited by 194 publications
(67 citation statements)
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“…These steps are important to the Chalk-Harrod and modified Chalk-Harrod mechanisms for olefin hydrosilation reactions that were first elucidated for platinum catalysts in the 1960's. [17] A closely related mechanism for rhodium-catalyzed ketone hydrosilations was proposed by Ojima in 1975. [18] These mechanisms allow for efficient catalysis, but the requirement of two-electron oxidative addition/reductive elimination steps has largely limited the range of available catalysts to platinum group metals.…”
Section: Summary and Outlook 31mentioning
confidence: 99%
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“…These steps are important to the Chalk-Harrod and modified Chalk-Harrod mechanisms for olefin hydrosilation reactions that were first elucidated for platinum catalysts in the 1960's. [17] A closely related mechanism for rhodium-catalyzed ketone hydrosilations was proposed by Ojima in 1975. [18] These mechanisms allow for efficient catalysis, but the requirement of two-electron oxidative addition/reductive elimination steps has largely limited the range of available catalysts to platinum group metals.…”
Section: Summary and Outlook 31mentioning
confidence: 99%
“…[17] A closely related mechanism for rhodium-catalyzed ketone hydrosilations was proposed by Ojima in 1975. [18] These mechanisms allow for efficient catalysis, but the requirement of two-electron oxidative addition/reductive elimination steps has largely limited the range of available catalysts to platinum group metals. These catalysts are expensive and have additional drawbacks such as a tendency to engage in β-hydride eliminations that can lead to the formation of undesired side-products (e.g., those derived from olefin isomerization).…”
Section: Summary and Outlook 31mentioning
confidence: 99%
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