Refined alteration of active sites via O modification on CoP/Co2P@Carbon hetero-structural catalyst for hydrogen generation

Zhang, Huanhuan; Liu, Yanyan; Zhou, Limin; Wei, Huijuan; Wen, Hao; Wang, Zhenggang; Yue, Xinzheng; Wu, Xianli; Liu, Baozhong; Fan, Yanping; Cao, Huaqiang; Jiang, Jianchun; Li, Baojun

doi:10.1016/j.apcatb.2022.122324

Cited by 33 publications

(5 citation statements)

References 54 publications

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“…76 Additionally, some researchers intentionally fabricate heterostructures of MPs with different M/P ratios to harness unique interfacial effects. Notably, the interfaces of CoP/Co 2 P and Ni 2 P/Ni 12 P 5 are highly active in NH 3 BH 3 hydrolysis 82 and HER, 83 respectively.…”

Section: Tuning the Synthesis Parametersmentioning

confidence: 99%

Metal Phosphide: An Atypical Catalytic Site

Liu,

Lan,

Zhong

et al. 2024

ACS Catal.

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The studies of metal phosphides (MPs) have flourished in the past decades due to their exceptional catalytic performance in thermo-, electro-, and photocatalysis. In this review, we summarize the synthesis methods of MPs and attribute their unique catalytic properties to electronic, geometric, and synergetic modifications. The multifunctionality of phosphorus doping makes phosphide an atypical catalyst. The phosphorus withdraws electrons from metal sites, isolates metal sites, and provides synergetic sites simultaneously, leading to high catalytic activities in various reactions, such as hydroformylation, hydrogen evolution reaction (HER), and photocatalytic H 2 production. The variety of MPs enables rational design of catalysts based on the requirements of different reactions and expands the application scenarios of MPs. This review summarizes the structure−performance relationship of MPs, paving the way for future catalyst design and mechanism studies.

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Section: Tuning the Synthesis Parametersmentioning

confidence: 99%

Metal Phosphide: An Atypical Catalytic Site

Liu,

Lan,

Zhong

et al. 2024

ACS Catal.

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“…Noble metal comprehensive application is restricted owing to their scarcity and valuableness. [17] Non-noble metal (Ni, [18] Co, [10,19] Cu, [20] Fe [21] ) catalysts with relatively low price and high abundance also have the same excellent catalytic performance for AB hydrolysis. The development of non-noble metal-based catalysts with high performances including high activity robust stability, and controllable synthesis is the main research direction in the future.…”

Section: Introductionmentioning

confidence: 99%

Amorphous Nickel Nanofilms for Efficient Hydrogen Generation from ammonia borane

Chen,

Li,

Guan

et al. 2024

Eur J Inorg Chem

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Clean and sustainable hydrogen production through liquid hydrogen storage material requires highly active and stable earth‐abundant non‐noble metal to replace expensive and rare noble metals. Herein, nickel nanofilms (Ni/NiO‐NFs) were prepared by the ionic liquid/water interface route. The cationic carbon chain length of the ionic liquid affects the phase composition of the nickel nanofilm, and the ionic liquid with [OMIm][PF6] as the anion has good thermal stability during the synthesis process. The efficiency of Ni/NiO‐NFs catalysts was tested by comparative kinetic analysis of the AB hydrolysis for hydrogen production. The as‐preparedNi/NiO‐NFs catalyst exhibits excellent hydrogen generation performances, including a hydrogen production rate (2917 ml min‐1 gNi‐1), and a low activation energy (48.1 kJ/mol). The transition of nickel oxide to metallic nickel and the destruction of the catalyst structure is responsible for the decreased durability. This work highlights the significance of amorphous nanofilms catalysts via the ionic interface method on the regulation of activity for AB hydrolysis.

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“…There is an appealing solution for promoting AB hydrolysis by means of harvesting and converting sunlight when suitable catalysts are adopted. Under low-temperature conditions, the H 2 release rate from AB hydrolysis was remarkably enhanced by the rational design of photocatalysts such as Ni–Pt/P–TiO 2 and cobalt phosphides. − Compared to the supported Pt-, Rh-, and Ru-based nanocatalysts, the activity of Cu-based nanocatalysts at room temperature is still lower, but it can be enhanced by light illumination via localized surface plasmon resonance (LSPR). ,, LSPR undergoes nonradiative decay and then produces energetic electron–hole pairs (hot carriers). Photogenerated hot carriers are able to participate in the activation of H 2 O molecules, which is considered to be the rate-determining step (RDS) of AB hydrolysis. ,− From the thermodynamics perspective, the thermal energy always contributes to the hydrolysis reaction with an Arrhenius-like dependence.…”

Section: Introductionmentioning

confidence: 99%

Hydrolysis of Ammonia Borane Using a Carbon Dot-Mediated Cu–Cu₂O Nanocatalyst Enabled with Photothermal and Photocatalytic Coupling

Ren,

Li,

et al. 2024

ACS Appl. Nano Mater.

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Hydrolysis of stable hydrogen-rich ammonia borane (AB) enables the rapid release of large amounts of hydrogen, but this always requires the presence of expensive noble metal-based nanocatalysts, hindering the practical utilization of AB. Here, we use carbon dots (CDs) to modulate components of Cu-based nanocomposite as a low-cost and high-activity nanocatalyst for the hydrolysis of AB. To further accelerate the hydrolysis reaction of AB, an interfacial photothermal and photocatalytic coupling system is designed with CD-modulated Cu-based nanocomposites for realizing the multipronged effects in the activation of H 2 O and hydrogen evolution reactions from AB solution. Under a simulated sunlight irradiation of 1 kW m −2 , the maximum volume of hydrogen production for this system reaches 783 mL•g −1 •cm −2 , which is above triple that of the traditional catalyst-suspended state. Moreover, this coupling system possesses superior stability and is easily recycled without the burden of high energy consumption and complex installation. Our presented method provides a feasible path for designing multifunctional nanocatalysts and accelerating catalytic reactions.

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Refined alteration of active sites via O modification on CoP/Co2P@Carbon hetero-structural catalyst for hydrogen generation

Cited by 33 publications

References 54 publications

Metal Phosphide: An Atypical Catalytic Site

Metal Phosphide: An Atypical Catalytic Site

Amorphous Nickel Nanofilms for Efficient Hydrogen Generation from ammonia borane

Hydrolysis of Ammonia Borane Using a Carbon Dot-Mediated Cu–Cu₂O Nanocatalyst Enabled with Photothermal and Photocatalytic Coupling

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Refined alteration of active sites via O modification on CoP/Co2P@Carbon hetero-structural catalyst for hydrogen generation

Cited by 33 publications

References 54 publications

Metal Phosphide: An Atypical Catalytic Site

Metal Phosphide: An Atypical Catalytic Site

Amorphous Nickel Nanofilms for Efficient Hydrogen Generation from ammonia borane

Hydrolysis of Ammonia Borane Using a Carbon Dot-Mediated Cu–Cu2O Nanocatalyst Enabled with Photothermal and Photocatalytic Coupling

Contact Info

Product

Resources

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Hydrolysis of Ammonia Borane Using a Carbon Dot-Mediated Cu–Cu₂O Nanocatalyst Enabled with Photothermal and Photocatalytic Coupling