Refinement of sensitive azides via in situ generated azole-based metal–organic frameworks towards stable energetic materials

Abstract

Energetic materials (EMs) have been widely employed in both military and civilian areas for nearly two centuries. The introduction of high-energy azide anions to assemble energetic metal−organic frameworks (EMOFs) is...

Nitrate anions embedded in rigid and cationic 3D energetic MOFs constructed by the chelating ligand towards insensitive energetic materials

“…into N-rich organic molecules. 20–22 However, these approaches always inevitably suffer from the high mechanical sensitivities of EMs because the sensitive groups cannot generally be well protected by the structure of organic molecule frameworks. 23–26…”