“…Reflectance Anisotropy Spectroscopy (RAS), a differential optical technique successfully applied to MBE and MOVPE growth of III-V compounds, could offer this opportunity [12]. In its pristine application, the exceptional sensitivity of RAS to optical anisotropy signals has been exploited to investigate the layerby-layer deposition during the growth, for example, of GaAs(001) [13], GaP(001) [14], InGaAs(001) [15], as well as to characterize clean surfaces of semiconductors [16][17][18], metals [19], insulating materials [20] and This is the author's peer reviewed, accepted manuscript. However, the online version of record will be different from this version once it has been copyedited and typeset.…”