Electromagnetic fields at the surface of a chiral negative refraction medium (the chirality parameter is larger than the refractive index) are analyzed theoretically. For obtaining chirality parameter,the normalized reflected and transmitted powers as a function of the incident angle are given for the perpendicular (TE) and parallel (TM) polarized incident wave.Brewster angle and total internal reflection angle are discussed. Due to the negative refraction of one eigen-wave in the chiral medium, the reflection, transmission and Brewster angle characteristics are very different from those in the normal chiral medium.In 1968, Veselago [1] studied the negative-refractive-index material (NIM) with simultaneously negative permittivity and negative permeability theoretically for the first time. Recently, NIM has been made in experiment [2] and the research on NIM becomes a hot topic. NIM has many potential applications in the areas of information, communication and so on. The negative refraction in the chiral medium is a new hot research [3] . The chirality parameter in the natural or synthetical chiral medium is always small, so an unnecessary restriction that the chiral parameter must be smaller than the refractive index was imposed in some literatures [4] . Since the refractive index could be negative, this restriction should be invalid. More recently, researches show that the chirality parameter can be larger than refractive index at least near the resonant frequency, and then one eigen-wave in the chiral medium will become a backward wave, making negative refraction in the chiral medium possible [5][6] . Due to the large chirality parameter, many problems related to electromagnetic propagation should be reconsidered theoretically. Based on the previous researches about the reflection and refraction at the surface of normally chiral medium, we analyzed the reflection and transmission characteristics at the surface of a chiral negative refractive mudium (the chirality parameter is larger than its refractive index) using constitutive relations different from Refs. [7,8]. Some novel characteristics different from those in the normally chiral medium are discovered.