Density, viscosity and sound velocity of six binary liquid mixtures of methanol, ethanol, propanol, butanol, hexanol and octanol with 1,4-dioxane have been measured over the entire range of composition at temperature 303.15K. From the experimental densities, viscosities and sound velocity, the excess molar volume (V E ), deviation in viscosity (Δη) and deviation in isentropic compressibility (ΔK S ) have been calculated. The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures.