Particles with diameters
smaller than 2.5 μm (PM2.5) can penetrate the respiratory
system and have negative impacts
on human health. Filter media with a porous surface and nanofiber/nanonet
structure demonstrate superior filtration performance compared to
traditional nano- and microfiber-based filters. In this study, nanostructured
filters were produced using the electroblowing method from solutions
containing different ratios of poly(vinylidene fluoride) (PVDF) and
polyethylene glycol (PEG) polymers for the first time. By increasing
the water-soluble PEG ratio in PVDF/PEG blend nanofibers and employing
a water bath treatment to the produced mat afterward, a more porous
fibrous structure was obtained with a lower average fiber diameter.
Notably, the removal of PEG from the PVDF/PEG (3–7) sample,
which had the highest PEG content, exhibited clustered nanofiber-/nanonet-like
structures with average diameters of 170 and 50 nm at the points where
the fibers intersect. Although this process resulted in a slight decrease
in the filtration efficiency (−1.3%), the significant reduction
observed in pressure drop led to a 3.2% increase in the quality factor
(QF). Additionally, by exploiting the polarizability of PVDF under
an electric field, the filtration efficiency of the nanostructured
PVDF filters enhanced with a ratio of 3.6% after corona discharge
treatment leading to a 60% improvement in the QF. As a result, the
PVDF/PEG (3–7) sample presented an impressive filtration efficiency
of 99.57%, a pressure drop (ΔP) of 158 Pa,
and a QF of 0.0345 Pa–1.