2023
DOI: 10.1002/chem.202203950
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Regio‐ and Stereoselective Carbon‐Boron Bond Formation via Heterogeneous Palladium‐Catalyzed Hydroboration of Enallenes

Abstract: A highly efficient regio‐ and stereoselective heterogeneous palladium‐catalyzed hydroboration reaction of enallenes was developed. Nanopalladium immobilized on microcrystalline cellulose (MCC) was successfully employed as an efficient catalyst for the enallene hydroboration reaction. The nanopalladium particles were shown by HAADF‐STEM to have an average size of 2.4 nm. The cellulose‐supported palladium catalyst exhibits high stability and provides vinyl boron products in good to high isolated yields (up to 90… Show more

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