Regioisomeric Benzidine‐Fullerenes: Tuning of the Diverse Hole‐Distribution to Influence Charge Separation Patterns

Abstract

Understanding the influence of molecular structure on charge distribution and charge separation (CS) provides essential guidance for optoelectronic materials design. Here we propose a regioisomeric strategy to tune the diverse hole-distribution, and probe the influence on CS patterns. Para-, meta-and orthosubstituted benzidine-fullerene, named 1 p, 1 m and 1 o are designed. Following CS, hole-delocalization occurs in 1 p, while hole-localization exists in 1 m and 1 o. The rates of charge separation (4.02 × 10 11 s À 1 ) and recombination (9.8 × 10 9 s À 1 ) of 1 p is about 20 and 12 times faster than 1 m and 1 o, indicating that para-determined delocalization promotes ultrafast CS, while meta-and ortho-generated localization contributes to long-lived CS states. Computational analysis further implies that localization results from the destruction of electronic conjugation for 1 m, and limitation of conformational relaxation for 1 o. Given that the universality and simplicity of regional isomerism, this work opens up new thoughts for molecular design with tunable charge separation patterns.

Ferrocene-Functionalized Fulleropyrrolidine Derivative: A Performance Enhancer for Solid-State Electrochromic Devices

“…The ferrocene-functionalized fulleropyrrolidine derivative Fullerene-Fc was synthesized according to the reported procedure. 37 The reaction of β-chloroferroceneacrolein (β-chloro-Fc-acrolein) and fullerene (C 60 ) in toluene with excess Nmethylglycine (sarcosine) via a 1,3-dipolar cycloaddition reaction (Prato reaction 38,39 ) resulted in the formation of Fullerene-Fc in 30% yield (Schemes 1 and S1, SI). Fullerene-Fc was purified by column chromatography and wellcharacterized by 1 H NMR, 13 C NMR spectroscopy, and HRMS techniques (Figures S1−S3, SI).…”