The ability of plastics to consume
CO2 captured in industries
while being pyrolyzed is extremely valuable. In this paper, the gasification
and carbon fixation of polypropylene (PP) and polycarbonate (PC) during
pyrolysis in a CO2 atmosphere at different temperatures
and reaction times were investigated. At the same time, other plastics
are pyrolyzed in the CO2 environment to compare the carbon
fixation capacity of the plastics, including polylactic acid plastic
and polystyrene plastic. The results showed that after a 30-min reaction
time at 750 °C, the carbon conversion efficiency (CE) of PP plastic
and PC plastic reaches 45.1% and 32%, respectively. When the temperature
is 600 °C, PP plastic can fix carbon, and the longer the reaction
time, the greater the effect of temperature. Furthermore, when PC
plastic and PP plastic are copyrolyzed, the presence of PC plastic
will reduce the carbon fixation ability of PP plastic, and it was
found that only plastic polymers with very little oxygen content were
able to fix CO2 in the pyrolysis process. Pyrolysis of
PP plastic and PC plastic also produces fused-ring aromatic compounds
such as naphthalene and anthracene and carbon microspheres.