2004
DOI: 10.1002/chin.200409070
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Regioselective Friedel—Crafts Alkylation of Anilines and Amino‐Substituted Heteroarenes with Hexafluoroacetone Sesquihydrate.

Abstract: Regioselective Friedel-Crafts Alkylation of Anilines and Amino-Substituted Heteroarenes with Hexafluoroacetone Sesquihydrate. -The alkylation of anilines takes place regioselectively at the para position, and heteroarenes are attacked at the position β to the sp 2 -hybridized N-atom. Yields strongly depend on the electron density of the substrates. -(MASCIADRI*, R.; KAMER, M.; NOCK, N.; Eur.

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“…Both procedures proved to be very efficient for the preparation of the targeted N -phenyl tertiary amines. Compound 6 was prepared according to the published procedure …”
Section: Chemistrymentioning
confidence: 99%
“…Both procedures proved to be very efficient for the preparation of the targeted N -phenyl tertiary amines. Compound 6 was prepared according to the published procedure …”
Section: Chemistrymentioning
confidence: 99%