2024
DOI: 10.1002/ange.202411567
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Regioselektiver, photoredox‐katalysierter Wasserstoffisotopenaustausch an benzylischen Positionen

Martin Stinglhamer,
Jan Hendrik Kuhlmann,
Elisa Martinelli
et al.

Abstract: A highly regioselective visible light photoredox‐catalyzed hydrogen isotope exchange (HIE) of benzylic positions in both simple and complex molecules is reported. The process follows a dual catalytic approach using an acridinium photocatalyst in combination with a thiol‐based hydrogen atom transfer catalyst, while the use of D2O as an isotope source ensures operational simplicity and cost‐effectiveness. High reactivity has been achieved for electron‐rich benzylic positions. Moreover, targeted radical formation… Show more

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