We classify all scalar-flat toric Kähler 4-manifolds under either of two asymptotic conditions: that the action fields decay slowly (or at all), or that the curvature decay is quadratic; for example we fully classify instantons that have any of the ALE-F-G-H asymptotic types. The momentum functions satisfy a degenerate elliptic equation, and under either asymptotic condition the image of the moment map is closed. Using a recent Liouville theorem for degenerate-elliptic equations, we classify all possibilities for the momentum functions, and from this, all possible metrics.