2023
DOI: 10.1039/d3dt01198d
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Regulating a Zn/Co bimetallic catalyst in a metal–organic framework and oxyhydroxide for improved photoelectrochemical water oxidation

Abstract: As one of the most popular photoanode materials, hematite (α-Fe2O3) has obvious advantages in the field of photoelectrochemical water splitting (PEC-WS). However, it is difficult to obtain excellent PEC-WS performance...

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Cited by 11 publications
(2 citation statements)
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“…The Co 2+ ion in the PMS system activation has proven to be best because it delivers an excellent degradation performance, which is significantly higher than the classical method of degradation. 14,15 However, dissolved homogeneous Co 2+ has an adverse pathogenic effect because it can osmose into the environment as a secondary pollutant. Therefore, in order to conquer the shortcomings of Co 2+ homogeneous systems, several cobaltic oxides, e.g., CoO, Co 3 O 4 , Co 2 O 3 , CoOOH, etc., and cobalt-containing binary oxides, e.g., Co 2 MnO 4 , CoFe 2 O 4 , FeCo 2 O 4 , and Co 2 TiO 2 , have been widely synthesized as heterogeneous catalysts for the activation of PMS.…”
Section: ■ Introductionmentioning
confidence: 99%
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“…The Co 2+ ion in the PMS system activation has proven to be best because it delivers an excellent degradation performance, which is significantly higher than the classical method of degradation. 14,15 However, dissolved homogeneous Co 2+ has an adverse pathogenic effect because it can osmose into the environment as a secondary pollutant. Therefore, in order to conquer the shortcomings of Co 2+ homogeneous systems, several cobaltic oxides, e.g., CoO, Co 3 O 4 , Co 2 O 3 , CoOOH, etc., and cobalt-containing binary oxides, e.g., Co 2 MnO 4 , CoFe 2 O 4 , FeCo 2 O 4 , and Co 2 TiO 2 , have been widely synthesized as heterogeneous catalysts for the activation of PMS.…”
Section: ■ Introductionmentioning
confidence: 99%
“…Co and Fe are the most efficient choices among all of these transition-metal catalysts. The Co 2+ ion in the PMS system activation has proven to be best because it delivers an excellent degradation performance, which is significantly higher than the classical method of degradation. , However, dissolved homogeneous Co 2+ has an adverse pathogenic effect because it can osmose into the environment as a secondary pollutant. Therefore, in order to conquer the shortcomings of Co 2+ homogeneous systems, several cobaltic oxides, e.g., CoO, Co 3 O 4 , Co 2 O 3 , CoOOH, etc., and cobalt-containing binary oxides, e.g., Co 2 MnO 4 , CoFe 2 O 4 , FeCo 2 O 4 , and Co 2 TiO 2 , have been widely synthesized as heterogeneous catalysts for the activation of PMS. , Due to their significant advantages like the ease of separation, recyclability of the solid nanocatalyst, comparatively less pollution, and cost-effectiveness, they can be considered as excellent alternatives to the homogeneous Co 2+ system .…”
Section: Introductionmentioning
confidence: 99%