Regulation of MIL-88B(Fe) to design FeS2 core-shelled hollow sphere as high-rate anode for a full sodium-ion battery

Ma, Linlin; Hou, Baoxiu; Zhang, Hui; Shi-tao, Yuan; Zhao, Lei; Liu, Yuan; Qi, Xin-Ran; Liu, Haiyan; Zhang, Shuaihua; Song, Jianjun; Zhao, Xiaoxian

doi:10.1016/j.cej.2022.139735

Cited by 31 publications

(4 citation statements)

References 55 publications

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“…Figure B depicts the first three cycles of GCD curves for the CoS 2 /FeS-10 electrode recorded at 1.0 A g –1 from 0.01 to 3 V. It is found that the discharge and charge platforms are basically consistent with the peak positions of the CV curves. Besides, the CoS 2 /FeS-10 electrode exhibits discharge/charge capacities as high as 533/476 mAh g –1 for the first cycle, revealing a relatively high ICE of 89.3%, which is much higher than those of recently reported metal sulfide-based anode materials, as listed in Table S3. ,,− The possible reason for the relatively high ICE for the CoS 2 /FeS-10 electrode is most likely due to the accelerated charge transfer ability across the interface of the heterostructure with the formation of the built-in electric field …”

Section: Resultsmentioning

confidence: 85%

Ion-Exchange Route Induced Heterostructured CoS₂/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Liu

Sun

et al. 2023

ACS Appl. Nano Mater.

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As a result of the high theoretical capacities, transition metal sulfides have attracted increasing attention as potential anodes for sodium-ion batteries (SIBs), but severely suffer from large volumetric variations, sluggish kinetics, and polysulfide shuttling. Herein, utilizing metal–organic frameworks (MOFs) as functional templates, heterostructured CoS2/FeS nanoparticles confined in a hollow N-doped carbon framework are successfully fabricated via a controlled ion-exchange reaction combined with subsequent carbonization and sulfurization processes. The construction of CoS2/FeS heterointerfaces promotes electron transfer and provides more active sites, while the derived N-doped carbon framework with a unique hollow interior effectively improves the electrical conductivity, alleviates the volumetric variations, and facilitates the sodium storage process with shortened Na+ diffusion paths. As anodes for SIBs, the optimal CoS2/FeS hybrid composite exhibits a high initial Coulombic efficiency (ICE) of 89.3%, a prolonged cycle life with a capacity of 494 mAh g–1 over 500 cycles under a current density of 1.0 A g–1, and an excellent rate capability of 428 mAh g–1 at 5.0 A g–1, showing the great promise for SIBs. This research offers an efficient and feasible approach for exploring and fabricating bimetallic sulfide heterostructures with a unique hollow structure for high-performance metal-ion batteries.

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Section: Resultsmentioning

confidence: 85%

Ion-Exchange Route Induced Heterostructured CoS₂/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Liu

Sun

et al. 2023

ACS Appl. Nano Mater.

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“…Yan et al synthesized SnS/C nanofiber membrane, the capacity is 324 mA h g –1 at 0.2 A g –1 after 200 cycles . In previously reports, it has been demonstrated that the hollow structure is a promising solution for accommodating volume changes during the charge/discharge process, ultimately improving the rate performance and cyclic stability. − …”

Section: Introductionmentioning

confidence: 99%

Flexible Self-Supporting MOF-Based Bean Pod Cube Hollow Nanofibers for Ultralong Cycling and High Rate Na Storage

Wu,

Long,

Dai

et al. 2024

ACS Appl. Mater. Interfaces

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Sodium-ion batteries (SIBs) have garnered significant attention due to their potential as an emerging energy storage solution. Tin sulfide (SnS) has emerged as a promising anode material for SIBs due to its impressive theoretical specific capacity of 1022 mA h g −1 and excellent electrical conductivity. However, its practical application has been hindered by issues such as large volume expansion, which adversely affects cycling stability and rate performance during the charge/discharge processes. In this study, a novel approach to address these issues by synthesizing the bean pod cube hollow metal−organic framework (MOF)-SnS x /NC@Ndoped carbon nanofibers through a process involving electrospinning, PDA coating, and calcination. The Sn-MOF serves as a selfsacrificing template, facilitating the simultaneous dissociation of MOF and polymerization of dopamine, leading to the creation of hollow intermediates that retain tin components. Subsequent sulfidation results in the integration of the hollow MOF-SnS x /NC nanoparticles within 3D nitrogen-doped carbon nanofibers, forming the distinctive bean pod cube composite structure. This unique configuration effectively shortens the diffusion path and mitigates volume expansion for sodium ions, ultimately yielding an exceptional high rate performance of 130 mA h g −1 (10 A g −1 ) and an ultralong cycling performance of 328 mA h g −1 even after 3500 cycles (2 A g −1 ) as the anode for SIBs.

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“…Especially, the large transition state energy barriers of conversion reaction between 2H and 1T, and from MoS 2 to Na 2 S and Mo, [7–9] result in poor rate capability. Besides, the shuttle effect of sodium polysulfide produced by Na 2 S restrains the reversible electrochemical reaction, [10] and the big volume variation during sodiation/desodiation process causes collapse of the structure, leading to poor cyclic stability [11,12] …”

Section: Introductionmentioning

confidence: 99%

“…Besides, the shuttle effect of sodium polysulfide produced by Na 2 S restrains the reversible electrochemical reaction, [10] and the big volume variation during sodiation/desodiation process causes collapse of the structure, leading to poor cyclic stability. [11,12] Rational nanostructure design has been proved fruitful in improving both the structure stability and reaction kinetics of materials. Wherein, hollow multishelled structure (HoMS) with multiple shells and interior cavities, has shown great promise in various application areas, including not only rechargeable batteries, [13][14][15] but also electromagnetic wave absorption, [16,17] catalysis, [18][19][20] sensor, [21,22] and drug delivery, [23,24] etc.…”

Section: Introductionmentioning

confidence: 99%

MoS₂ Hollow Multishelled Nanospheres Doped Fe Single Atoms Capable of Fast Phase Transformation for Fast‐charging Na‐ion Batteries

Zhang,

Guo

et al. 2024

Angewandte Chemie

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Low Na+ and electron diffusion kinetics severely restrain the rate capability of MoS2 as anode for sodium‐ion batteries (SIBs). Slow phase transitions between 2H and 1T, and from NaxMoS2 to Mo and Na2S as well as the volume change during cycling, induce a poor cycling stability. Herein, an original Fe single atom doped MoS2 hollow multishelled structure (HoMS) is designed for the first time to address the above challenges. The Fe single atom in MoS2 promotes the electron transfer, companying with shortened charge diffusion path from unique HoMS, thereby achieving excellent rate capability. The strong adsorption with Na+ and self‐catalysis of Fe single atom facilitates the reversible conversion between 2H and 1T, and from NaxMoS2 to Mo and Na2S. Moreover, the buffering effect of HoMS on volume change during cycling improves the cyclic stability. Consequently, the Fe single atom doped MoS2 quadruple‐shelled sphere exhibits a high specific capacity of 213.3 mAh g‐1 at an ultrahigh current density of 30 A g‐1, which is superior to previously‐reported results. Even at 5 A g‐1, 259.4 mAh g‐1 (83.68 %) was reserved after 500 cycles. Such elaborate catalytic site decorated HoMS is also promising to realize other “fast‐charging” high‐energy‐density rechargeable batteries.

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Regulation of MIL-88B(Fe) to design FeS2 core-shelled hollow sphere as high-rate anode for a full sodium-ion battery

Cited by 31 publications

References 55 publications

Ion-Exchange Route Induced Heterostructured CoS₂/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Ion-Exchange Route Induced Heterostructured CoS₂/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Flexible Self-Supporting MOF-Based Bean Pod Cube Hollow Nanofibers for Ultralong Cycling and High Rate Na Storage

MoS₂ Hollow Multishelled Nanospheres Doped Fe Single Atoms Capable of Fast Phase Transformation for Fast‐charging Na‐ion Batteries

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Regulation of MIL-88B(Fe) to design FeS2 core-shelled hollow sphere as high-rate anode for a full sodium-ion battery

Cited by 31 publications

References 55 publications

Ion-Exchange Route Induced Heterostructured CoS2/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Ion-Exchange Route Induced Heterostructured CoS2/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Flexible Self-Supporting MOF-Based Bean Pod Cube Hollow Nanofibers for Ultralong Cycling and High Rate Na Storage

MoS2 Hollow Multishelled Nanospheres Doped Fe Single Atoms Capable of Fast Phase Transformation for Fast‐charging Na‐ion Batteries

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Ion-Exchange Route Induced Heterostructured CoS₂/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

Ion-Exchange Route Induced Heterostructured CoS₂/FeS Nanoparticles Confined in Hollow N-Doped Carbon Frameworks for Enhanced Sodium Storage Performance

MoS₂ Hollow Multishelled Nanospheres Doped Fe Single Atoms Capable of Fast Phase Transformation for Fast‐charging Na‐ion Batteries