Regulation of stability and detonation performance: preparation of coordination compounds by using isomeric ligands

Abstract

In order to resolve the conflict between mechanical sensitivity and explosive performance, we utilized a retro-synthesis approach to design and synthesize ligand 1H-imidazole-4-carbohydrazide (4-IMCA) and complex Cu(4-IMCA)2(ClO4)2 (ECCs-1). The structure...

N^N^C-Cyclometalated rhodium(iii) complexes with isomeric pyrimidine-based ligands: unveiling the impact of isomerism on structural motifs, luminescence and cytotoxicity

“…Despite various kinds of constitutional and configurational isomerism of metal complexes being well known, 40 ligand isomerism, which belongs to constitutional isomerism, is documented in literature to a considerably lesser extent than other types of the isomerism of complexes. 23,41–64…”