Thermoelectric materials, as clean energy materials,
can directly
convert thermal energy into electrical energy. These materials have
received significant attention owing to their environmentally friendly
nature. Skutterudite thermoelectric materials feature excellent electrical
properties and great potential for environmentally friendly and industrial
applications. The thermal performance optimization of skutterudite
is mainly achieved through framework atom substitution, lattice void
filling, and recombination of nano second-phase. In this study, the
significant optimization of the thermal properties of S0.05Co4Sb11.6Te0.4 with fullerene-C60 as a nano second-phase composite material was reported.
At 773 K, the N-type 0.10C60-S0.05Co4Sb11.6Te0.4 (0.10C60-SKD) polycrystalline
material featured a dimensionless figure of merit zT value of 1.34, which is 31% higher than that of the matrix material.
The overall optimization of the thermoelectric properties of the material
was achieved through the high-pressure and high-temperature (HPHT)
synthesis method, combined with electronegative S element filling,
Te element substitution, and the recombination of C60 nano
second-phase. The experimental results indicated that the incorporation
of C60 resulted in the formation of finer grains in the
composite material with significant lattice distortion, dislocations,
and abundant grain boundaries in its microstructure. Various phonon
scattering mechanisms occurred within the material, effectively reducing
the lattice thermal conductivity of the material. The stable structure
of C60 molecules added to the matrix material can optimize
the mechanical properties of the material. The composite sample with
a C60 amount of 0.20 exhibited a Vickers hardness of 7.01(1)
GPa. This study employed the HPHT method for the direct synthesis
of C60 composite samples within 30 min and provides insights
into improving the thermoelectric properties of skutterudite.