The present work investigates the structure of fast supersonic turbulent flames typically observed as precursors to the onset of detonation. These high speed deflagrations are obtained after the interaction of a detonation wave with cylindrical obstacles. Two mixtures having the same propensity for local hot spot formation were considered, namely hydrogen-oxygen and methane-oxygen. It was shown that the methane mixture sustained turbulent fast flames, while the hydrogen mixture did not. Detailed high speed visualizations of nearly two-dimensional flow fields permitted to identify the key mechanism involved. The strong vorticity generation associated with shock reflections in methane permitted to drive jets. These provided local enhancement of mixing rates, sustenance of pressure waves, organization of the front in stronger fewer modes and eventually the transition to detonation. In the hydrogen system, for similar thermo-chemical parameters, the absence of these jets did not permit to establish such fast flames. This jetting slip line instability in shock reflections (and lack thereof in hydrogen) was correlated with the value of the isentropic exponent and its control of Mach shock jetting instability (Mach & Radulescu).