Rejected Sago Starch as a Coating Material to Mitigate Urea-Nitrogen Emission

Abstract

Urea–nitrogen is commonly lost through ammonia (NH3) volatilization, denitrification, and nitrate (NO3−) leaching. Rejected sago starch (RSS), which is a by-product of sago flour extraction, could be used to minimize NH3 volatilization from urea. Urea granules were coated with different concentrations of RSS (2%, 3%, 4%, 5%, and 6%), and their effects on NH3 emission, soil pH, exchangeable ammonium (NH4+), and available NO3− were determined. The urea was coated with RSS and homogenized using a mini rotary machine. The RSS-coated urea granules were dyed to differentiate their concentrations. The effectiveness of the RSS as a coating material was determined using a closed-dynamic air flow system. The soil used in the NH3 volatilization was the Bekenu series (Sandy loam, Typic Paleudults). This study compared seven different mixture treatments: soil alone (S), 5 g of uncoated urea (U), 5 g of 2% RSS-coated urea (CU1), 5 g of 3% RSS-coated urea (CU2), 5 g of 4% RSS-coated urea (CU3), 5 g of 5% RSS-coated urea (CU4), and 5 g of 6% RSS-coated urea (CU5). Urea coated with RSS, particularly CU1, effectively minimized NH3 loss and improved the retention of soil exchangeable NH4+ and available NO3− compared with uncoated urea because the RSS serves as a barrier to minimizing the concentration of NH3 from urea hydrolysis. Urea could be coated with RSS at the 2% concentration to enhance urea–N efficiency through a reduction in NH3 emission from urea. RSS-coated urea could be an alternative for farmers because of its controlled release of N and economical benefits. Field planting using rice as a test crop to solidify the effectiveness of RSS-coated urea in improving N retention from urea is still ongoing.

Potential of Rejected Sago Starch as a Coating Material for Urea Encapsulation

“…There are currently eight sago processing factories in operation, mainly in the Mukah and Pusa (Sarawak) divisions, with an average production of up to 1.5 metric tonnes of sago starch per hour [56]. To complement and reduce the reliance on existing organic materials for urea coating, as summarized in Table 1, a natural polymer such as RSS could be considered an alternative coating material for urea because it is abundantly available, biodegradable, environmentally friendly, hydrophilic, and has a low cost and a weak coating barrier [57]. Apart from these factors, the physico-chemical properties of RSS are the most important.…”