This study explored the role of baseline reject control on transitivity responding. In Experiment 1, participants learned to respond to a baseline of arbitrary AB and AC conditional relations, and then they were exposed to transitivity‐like BC and CB trials in which the correct comparison stimulus was replaced by a novel stimulus (D). Five of 10 participants selected stimulus D, but only 1 showed expansion of the baseline stimulus classes to include the D stimuli. In Experiment 2, the emergence of symmetry and transitivity from baseline relations was assessed before participants were exposed to the transitivity‐like trials. Six of 8 participants who showed emergence of equivalence relations selected the D stimuli on transitivity‐like trials and provided evidence that baseline classes expanded to include these stimuli. In Experiment 3, these 6 participants selected novel stimuli (E) in additional transitivity‐like trials, and all showed that the E stimuli had become members of the previously established classes, which now comprised 5 members. A route for the emergence of transitivity by way of the transfer of baseline between‐classes reject control is discussed.