Popocatepetl Volcano is potentially devastating to populations living in the greater Mexico City area. Systematic monitoring of fumarole gases and flanking thermaVmineral springs began in early 1994 after increased fumarolic and seismic activity were noticed in 1991. These investigations had two major objectives: 1) to determine if changes in magmatic conditions beneath Popocatepetl might be reflected by chemical changes in fumarolic discharges and 2) to determine if thermaVminera1 spring waters in the vicinity of Popocatkpetl are geochemically related to or influenced by the magmatic system. This report summarizes results from these two discrete studies.Chemical and isotopic compositions of gases were monitored by placing alkaline traps containing 4N KOH around the crater and by collecting the trap solutions at near-monthly intervals until the volcano erupted on December 21,1994. Absolute abundances of volatile constituents (ppdday of C1, &tal, F, COz, Hg, and As) show general increases during the June-July 1994 and 0ct.-Dec. 1994 time periods. These increases correlated with increased SO2 output measured by correlation spectrometry (COSPEC). The full range of sulfur isotope compositions measured during this study is 1.5 to 6.4%0; the lower values generally occurred in the 0ct.-Dec. samples. These values are very close to that of mantle sulfur (-O%O). The higher values occurred in samples from the June-July period, suggesting possible incorporation of hydrothermal sulfate or underlying Cretaceous evaporitic rocks (roughly 16 to 19%0) into the magma during that time. Carbon isotope compositions measured on the trap solutions were not as useful because of contamination with atmospheric C02. Bulk chemistry and sulfur isotope variations of the volatiles can be explained by injection of mafic magma into a silicic magma chamber beneath the volcano, ascent of magma in the conduit or chamber, and incorporation of small volumes of altered rocks or older strata into the evolving melts.The flanking thermdmineral waters, which were collected periodically from May 1994 until June 1995, show no apparent geochemical changes with time, indicating that increased volcanic activity did not affect these springs. These fluids are relatively low in Si02, B, Br, Cs, Li, and Rb compared with those from known geothermal systems, indicating that Popocatepetl springs are not derived from a high-temperature reservoir. Chemical geothermometry of the waters and feeble gas emissions suggest equilibration temperatures of 160°C. The waters show chemical equilibrium with carbonate and evaporite minerals (calcite and gypsum), which are known to occur in regional Cretaceous strata. Limited stable isotope data on the waters indicate recharge at elevations considerably lower than Popocat6petl summit, whereas tritium contents indicate that the waters have maximum mean residence times of approximately 1000 years.