Authigenic clay mineral formation in fluvial sandstones and one brackish sandstone from the lower and middle Coal Measures of the East Midlands has been studied using XRD, optical microscopy and a variety of electron optical techniques. The sandstones are quartz-rich with minor feldspar and mica. The clay minerals present are kaolinite, chlorite and illite; they form 10-15% by volume of most of the sandstones. Both detrital and authigenic illite and chlorite are present but the kaolinite is entirely authigenic. Kaolinite and illite authigenesis has been important in all the sandstones but authigenic chlorite is only abundant in the phyllosilicate-rich Silkstone sandstone. The controlling factors in the diagenesis of the sandstones were primary composition, environment of deposition, bed thickness, pore-fluid migration and composition, pressure and temperature. These interacting factors have been of varying importance in time and space in the diagenesis of the sandstones. Authigenic clay morphology appears to have been controlled by time and environment of formation, pore fluid chemistry and, possibly, parent minerals.In the East Midlands the Westphalian Coal Measures consist of fluvial channel sands, channel abandonment silts, interdistributory silts, shales and coals, with occasional marine bands. In order to investigate the environmental and physico-chemical controls on mineral authigenesis in the Coal Measures sandstones, in particular the clay mineral authigenesis, core samples were obtained from five wells near Gainsborough in Lincolnshire (Fig. I). The wells straddle the gentle WSW-ENE-trending Walkeringham anticline. Ten fluvial sandstones were extensively sampled, of which the present paper is concerned chiefly with the five shown in Fig. 1. One brackish-water sandstone, the Silkstone (Fig. 1), was also sampled; it is known to be brackish from the presence of the Estheria band within the sandstone (Calver, 1968). Eight interfluvial and channel abandonment siltstone facies were sampled; only one sample of each siltstone was taken.
TECHNIQUESThe observations presented here were made using a light-optical microscope, a Jeol JSM 35 scanning electron microscope (SEM) with energy-dispersive X-ray analysis (EDAX) and cathodoluminescence analysis facilities, an AEI high-voltage electron microscope (HVEM), a Jeol 120 CX scanning transmission electron microscope (STEM) with EDAX, and a Jeol superprobe JXA 733 with wavelength-dispersive X-ray analysis which was used for backscattered electron imaging (BEI). All minerals named in the Figures were 9 1984 The Mineralogical Society