Relationship between Freundlich isotherm Coefficients, logKFand 1 /nfor atrazine desorption from soils in Japan

Ebato, Munehiro; Yonebayashi, Koyo

doi:10.1080/00380768.2003.10410325

Cited by 2 publications

(4 citation statements)

References 13 publications

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“…The amount of atrazine removed from an equilibrium solution after the first adsorption experiment was transformed into removed (predicted) ratio by calculations based on the amount of atrazine remaining in the equilibrium solution after the first adsorption experiment. If the ratio of atrazine removed from the equilibrium solution after the first adsorption experiment (predicted ratio) is the same as the ratio of atrazine desorbed from soil during the desorption experiments to the amount of atrazine first adsorbed onto soil (measurement ratio), it can be considered that reversible adsorption of atrazine occurred in the soil (Ebato and Yonebayashi 2002b). The results of the calculations are shown in Table 4.…”

Section: Resultsmentioning

confidence: 95%

“…Adsorption and desorption of atrazine and linuron by saline soils Based on the amount of solution exchanged during the desorption experiments, the amount of atrazine taken from a centrifuge tube could be calculated (Ebato and Yonebayashi 2002b). The amount of atrazine removed from an equilibrium solution after the first adsorption experiment was transformed into removed (predicted) ratio by calculations based on the amount of atrazine remaining in the equilibrium solution after the first adsorption experiment.…”

Section: Resultsmentioning

confidence: 99%

“…To analyze the effect of the soil characteristics on herbicide adsorption, we used the adsorption ratio (AR) as an indicator (Ebato and Yonebayashi 2002a). The equation for AR is as follows: Desorption experiments were conducted immediately after the adsorption process (Ebato and Yonebayashi 2002b). Following adsorption, 5 mL of the 0.01 mol L-1 CaCI 2 solution was added to replace the 5 mL of supernatant removed and the tubes were shaken for another 24 h after the soil was resuspended by agitation with a vortex mixer.…”

Section: Mater!ajls and Methodsmentioning

confidence: 99%

See 2 more Smart Citations

Estimation of buffering capacity of mangrove soils by using hydrophobic organic compounds, atrazine and linuron

Ebato

Matsui²,

Nomura

et al. 2004

Soil Science and Plant Nutrition

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Section: Resultsmentioning

confidence: 95%

Section: Resultsmentioning

confidence: 99%

Section: Mater!ajls and Methodsmentioning

confidence: 99%

See 1 more Smart Citation

Estimation of buffering capacity of mangrove soils by using hydrophobic organic compounds, atrazine and linuron

Ebato

Matsui²,

Nomura

et al. 2004

Soil Science and Plant Nutrition

Self Cite

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“…where log is the 10-based logarithm. A linear correlation is, therefore, expected between log K F and 1/ n . − …”

Section: Methodsmentioning

confidence: 95%

Halogen Bonding in Perfluoroalkyl Adsorption

Lu,

2024

ACS Omega

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Adsorption is a promising technology to remove perfluoroalkyl substances (PFAS), including perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA), from contaminated water. Although a large number of materials have been evaluated for PFAS adsorption, guidelines that can facilitate the rational design and selection of adsorbents have not been established due to the lack of a mechanistic understanding on the molecular level. Using a novel interpretation of the Freundlich isotherm, this study identifies halogen bonding as the main mechanism controlling perfluoroalkyl adsorption by using a materiomic approach that compares the electrostatic polarities of a variety of carbon, polymer, and mineral-based materials reported in the literature. Comparisons show that both PFOS and PFOA are favorably adsorbed by materials containing high densities of π electrons, lone electron pairs, and negative charges, consistent with the formation of halogen bonding between the positive σ-hole of fluorine as a Lewis acid and a nucleophilic solid as a Lewis base. The identification of this previously unappreciated noncovalent bonding mechanism offers fresh insight into the search of suitable materials for perfluoroalkyl adsorption.

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Relationship between Freundlich isotherm Coefficients, logK_Fand 1 /nfor atrazine desorption from soils in Japan

Cited by 2 publications

References 13 publications

Estimation of buffering capacity of mangrove soils by using hydrophobic organic compounds, atrazine and linuron

Estimation of buffering capacity of mangrove soils by using hydrophobic organic compounds, atrazine and linuron

Halogen Bonding in Perfluoroalkyl Adsorption

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