“…Thus, the magnetic contribution to the free energy of vacancy migration will be negative for Ni compositions less than ϳ78 pct and positive for Ni compositions greater than ϳ78 pct. Other Invar alloys, such as Fe 65 (Ni 1-x Mn x ) 35 , [44] Fe 60 Mn 40 , [45,46] Co 46 Mn 54 , [47] etc., also show a behavior of elastic constants similar to that of the Fe-Ni Invar alloy. Therefore, it is possible for these Invar alloys that the magnetic contribution to the free energy of vacancy migration below the Curie temperatures is also negative.…”