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To elucidate the air pollution, its features, its sources, and the influence of yellow sand (kosa) in Tsu City, the ion components and trace metals in precipitation at Mie University were measured along with their temporal changes. From the obtained correlation coefficients and the results of the principal component analysis, the ions and the trace metals in the precipitation were classified into three groups: the SSI group (the ions of Cl -, Na + , K + , Mg 2+ , ss-SO 4 2-and ss-Ca 2+ , of which the main sources were sea salt); the ASI group (the ions of F -, NO 3 -, NH 4 + , nss-SO 4 2-and nss-Ca 2+ , of which the main sources were anthropogenic pollution and soil); and the ASM group (trace metals of Al, Fe, Mn, Pb, and Zn, of which the main sources were anthropogenic pollution and soil). The concentrations of the SSI group tended to be higher with increased wind velocity. Results suggest that seawater was raised into the atmosphere in proportion to the wind velocity, and that the sea salt ions were transported and increased in the precipitation. The effects of long-range transport and local pollution on the pollutants and the soil elements in the precipitation were discussed from measurements of the concentration ratios of Pb and Zn (Pb/Zn) and backward trajectory analysis. The concentrations of ion components and trace metals during the rain events in Tsu City, Mie generally decreased over time. The condensed pollutants in the air are regarded as removed in the initial period of the rain events. We can confirm that the concentration ratios (Pb/Zn ratios) are almost identical to reported values for rain clouds through Japan. Only one day showed high rates of pollutants, but it is presumed to be not the effect of kosa but of the industrial zone to the north east of Tsu City.
To elucidate the air pollution, its features, its sources, and the influence of yellow sand (kosa) in Tsu City, the ion components and trace metals in precipitation at Mie University were measured along with their temporal changes. From the obtained correlation coefficients and the results of the principal component analysis, the ions and the trace metals in the precipitation were classified into three groups: the SSI group (the ions of Cl -, Na + , K + , Mg 2+ , ss-SO 4 2-and ss-Ca 2+ , of which the main sources were sea salt); the ASI group (the ions of F -, NO 3 -, NH 4 + , nss-SO 4 2-and nss-Ca 2+ , of which the main sources were anthropogenic pollution and soil); and the ASM group (trace metals of Al, Fe, Mn, Pb, and Zn, of which the main sources were anthropogenic pollution and soil). The concentrations of the SSI group tended to be higher with increased wind velocity. Results suggest that seawater was raised into the atmosphere in proportion to the wind velocity, and that the sea salt ions were transported and increased in the precipitation. The effects of long-range transport and local pollution on the pollutants and the soil elements in the precipitation were discussed from measurements of the concentration ratios of Pb and Zn (Pb/Zn) and backward trajectory analysis. The concentrations of ion components and trace metals during the rain events in Tsu City, Mie generally decreased over time. The condensed pollutants in the air are regarded as removed in the initial period of the rain events. We can confirm that the concentration ratios (Pb/Zn ratios) are almost identical to reported values for rain clouds through Japan. Only one day showed high rates of pollutants, but it is presumed to be not the effect of kosa but of the industrial zone to the north east of Tsu City.
(Received 6 February /994 and in revisedform /0 September /994) ...and / will cause to rain upon him, and upon his bands. and upon the many peoples that are with him, an overflowing shower, and great hailstones. fire and brimstone. Eukiel38:22Abstract. Recent concerns about the rapid deterioration in the quality of water resources in Israel, in addition to the widely documented anthropogenic acidification of precipitation in many parts of the world, have put a "state of the art" review of our knowledge of the chemistry of precipitation in Israel on the order of the day. Electrolyte content in precipitation in Israel is inversely related to average annual precipitation, and thus is 3-6 times higher in southern than in central Israel. The major reason for these differences is the differential enrichment in components of continental origin, such as Ca 2 + and HC0 3 -. The chemical composition of precipitation is determined by the balance between components of marine and continental origin. Na"and CI-are the major ions contributed by sea spray, and therefore most of the precipitation exhibits Na/CI (molar) ratios close to that of seawater. Precipitation in the southern parts of the country is an exception. Other ions of partly marine origin are Mg2+, sot, K+, and, to a limited extent, Ca 2 +. Marine contribution to precipitation decreases with distance from the sea. The most important component of continental origin in precipitation in Israel is Ca 2 +, similar to precipitation in other semiarid areas surrounding the Mediterranean. Calcium in precipitation is often associated with dryfall (dust) originating in North African desert areas. NH/ concentration levels are relatively low, and thus, the importance of this ion as an acidityneutralizing agent is small compared to central/northern Europe. Precipitation in Israel is neutral to mildly alkaline, with an average pH of 6.5 ± 0.8. Mildly alkaline rain is the rule in central and southern Israel. In the Golan Heights, Galilee, and the northern coastal region, most of the precipitation events are acidic. On Mt. Carmel, 40% of the rain events examined during three rainy seasons were strongly acid, and in more than 65% of the events, pH was~5.6. Acidity in precipitation in Israel is determined primarily by excess sot. Nitrates have only a subordinate role.Synoptic analysis as well as sulfur isotopic data suggest that the excess sulfate is a long-range import from over the Mediterranean Sea, either of anthropogenic European or of biogenic/marine dimethyl sulfide (DMS) origin. In southern Israel, an isotopic amount effect was observed, whereby rain in rainier years was isotopically lighter 0 18 0 than precipitation in the less rainy years. ol4S values of precipitation were found to be in the range of 0-15%0, thus indicating that precipitation sulfate consisted of a mixture of marine and nonmarine sulfate. CI and Sr isotope ratios in precipitation were determined as well.
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