A series of tracer tests has been carried out in the compost and limestoneTan-y-Garn Reducing and Alkalinity-Producing System (RAPS), designed to treat iron-rich net acidic mine water (mean pH 6.18, Fe = 47 mg L . Electrical conductivity and major ion chemistry were monitored for a 170 hour period.Sodium exhibited a retardation of 1.15 to 1.2 in the RAPS medium relative to chloride, due to cation exchange. Simple 1-D advection-diffusion analytical modelling succeeded in simulating the early portion of tracer breakthrough in the RAPS effluent. More complex analytical modelling, accounting for (i) mixing and dilution effects in the supernatant water input signature and (ii) matrix diffusion effects, was found to be required to adequately simulate the later-stage tail of the breakthrough curve in the RAPS effluent.
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KeywordsTracer test, alkalinity, mine water, artificial wetland, matrix diffusion, ion exchange 3
Introduction
What is a Reducing and Alkalinity-Producing System (RAPS)?It is common and cost-effective to treat iron-rich mine waters (Banks and Banks, 2001; PIRAMID Consortium, 2003;Sapsford and Watson, 2011) by passive, aerobic methods, such as aerobic sedimentation basins or wetlands.These function by the oxidation of ferrous to ferric iron, followed by the hydrolysis and precipitation of ferric iron from the water. This net process can be described by equation (1) The overall oxidation and hydrolysis reaction is thus acid-producing (2 moles of protons released for every mole of ferrous iron oxidised and precipitated).However, the hydrolysis and precipitation reaction is strongly pH-dependent: if the pH becomes too low, the hydroxide precipitate will not form. Thus, it is important that sufficient alkalinity is available in the water to absorb the protons produced and to buffer the pH at a reasonably high level (Hedin et al., 1994a;Younger et al., 2002). Alkalinity can be added actively, by dosing the influent mine water with hydroxide or carbonate. However, it can also be released passively by allowing the mine water to flow through limestone drains before entering the aerobic treatment lagoons or wetlands (PIRAMID Consortium, 2003). The limestone slowly dissolves, releasing bicarbonate alkalinity to the water. If the water contains oxygen, however, ferric hydroxide may precipitate out in the limestone drains, "armouring" the limestone clasts and inhibiting further dissolution (Hedin et al., 1994b;Cravotta and Trahan, 1999;Watzlaf et al., 2000a;Bernier et al., 2001). Thus, it is important to strip oxygen from the water before it enters the limestone drain, ensuring that iron remains in its ferrous form (Equation 2). This is most effectively done by a layer with a high organic content and thus a high oxygen demand -for example, a compost layer (represented by CH 2 O in equation (2)). On exiting a RAPS, the mine water will typically:(i) pass through a re-aeration system, such as an aeration cascade, before entering(ii) a system of aerobic treatment lagoons and/or wetlands, where the iron conte...