“…As is known, the presence of the labile oxygen [32,33] in the ReBa 2 Cu 3 O 7-d (Re=Y, or another rare earth ion) compounds, can contribute to the emergence of an non-equilibrium state, which can occur at high pressures [34,35], ''hopping'' changes in temperature [36,37] and long-term storage [38][39][40] and, in turn, may contribute to the process of phase separation [41,42], ascending diffusion [43,44] and the emergence of various kinds of superstructures [45,46]. All these processes have a significant impact on the physical properties of HTSC in the normal and in superconducting states.…”