“…An appropriate example from our own research is of high density polyethylene (HDPE), which in its pristine form exhibits a single second order transition, namely, T g . However, after undergoing a certain solid state crystallization stage, which results in crystalline restructuring, the same HDPE exhibits an untypically immense β transition in the amorphous phase [4,5]. In the present study we deal with yet another first order transition, namely the Brill transition in polyamides (e.g., nylon 66), for which a counterpart transition in the amorphous phase is explored.…”