In order to expand the possibilities of practical application of polymeric materials we studied syndiotactic 1,2-polybutadiene (1,2-SPB). The experimental procedure and the MV-002 device for determining the breakdown voltage and electrical breakdown of a polymer are described in detail. Mathematical models of the dependence of the breakdown voltage of the polymer on the frequency and magnitude of the electrical breakdown of the polymer on the thickness of the sample have been built and studied. Regression analysis was used for mathematical data processing. The reliability of the results obtained is proved by the methods of test statistics.