Relay Zn(<scp>ii</scp>)- and Au(<scp>i</scp>)-catalyzed aziridination/cyclization/ring expansion sequence to form 3-benzazepine derivatives

Liu, Rai‐Shung; Tanpure, Sudhakar Dattatray; Kardile, Rahul Dadabhau

doi:10.1039/d3qo00134b

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Relay Zn(ii)- and Au(i)-catalyzed aziridination/cyclization/ring expansion sequence to form 3-benzazepine derivatives

Abstract: Synthesis of 3H-benzo[d]azepine-2-carboxylates from 2-alkynylphenyl aldimines and α-diazo esters using Zn(II) and Au(I) catalysts is described. In this relay catalysis, Zn(II) catalyzes an addition of α-diazo ester to the imine...

Cited by 3 publications

References 90 publications

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