Releases from the International Association for the Properties of Water and Steam for calculating properties of steam, ordinary and heavy water substance and seawater

Alexandrov, A.; Orlov, K. G.; Butakova, M V

doi:10.1088/1742-6596/891/1/012329

Cited by 1 publication

(1 citation statement)

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“…The saturation vapour pressure (p sat ) in mmHg of the solution water-calcium nitrate at different salt fractions and temperatures can be found in Table A29 [35]: The specific heat (c p ) of the solution water-sodium hydroxide can be calculated using the following equation [36]:…”

Section: Saturated Pressurementioning

confidence: 99%

District Heating of Buildings by Renewable Energy Using Thermochemical Heat Transmission

Critoph

Pacho

2022

Energies

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The decarbonisation of building heating in urban areas can be achieved by heat pumps connected to district heating networks. These could be ‘third-generation’ (85/75 °C), ‘fourth-generation’ (50/40 or 50/25 °C) or ‘fifth-generation’ (near ambient) water loops. Networks using thermochemical reactions should require smaller pipe diameters than water systems and be more economic. This work investigates thermochemical transmission systems based on liquid–gas absorption intended for application in urban district heating networks where the main heat source might be a MW scale heat pump. Previous studies of absorption for heat transmission have concentrated on long distance (e.g., 50 km) transmission of heat or cold utilizing waste heat from power stations or similar but these are not directly applicable to our application which has not been investigated before. Absorbent-refrigerant pairs are modelled using water, methanol and acetone as absorbates. Thermodynamic properties are obtained from the literature and modelling carried out using thermodynamic analysis very similar to that employed for absorption heat pumps or chillers. The pairs with the best performance (efficiency and power density) both for ambient loop (fifth-generation) and high temperature (fourth-generation) networks use water pairs. The next best pairs use methanol as a refrigerant. Methanol has the advantage of being usable at ambient temperatures below 0 °C. Of the water-based pairs, water–NaOH is good for ambient temperature loops, reducing pipe size by 75%. Specifically, in an ambient loop, heat losses are typically less than 5% and the heat transferred per volume of pumped fluid can be 30 times that of a pumped water network with 10 K temperature change. For high temperature networks the heat losses can reach 30% and the power density is 4 times that of water. The limitation with water–NaOH is the low evaporating temperature when ambient air is the heat source. Other water pairs perform better but use lithium compounds which are prohibitively expensive. For high temperature networks, a few water- and methanol-based pairs may be used, but their performance is lower and may be unattractive.

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Section: Saturated Pressurementioning

confidence: 99%