A new multi−carrier orthogonal double bit rate differential chaotic shift keying (MC−ODBR−DCSK) communication system is presented in this paper. With two composite signals generated by an orthogonal chaotic signal generator as reference signals, 2M bits of information data are transmitted on M−channel subcarriers, improving transmission speed and energy efficiency. In addition, the receiver does not require a radio frequency (RF) delay circuit to demodulate the received data, which makes the system easier to implement. This paper analyzes Data−energy−to−Bit−energy Ratio (DBR) of the system. The bit error rate performance of the system is simulated to verify the impact of parameters such as chaotic maps, semi-spread spectrum factor, and sub-carrier number. At the same time, the bit error rate performance of the MC−ODBR−DCSK system is compared with traditional DCSK systems in Rician fading and additive Gaussian white noise (AWGN) channels.