Since the discovery of high-temperature superconductivity (SC) in quasi-two-dimensional copper oxides, a few layered compounds, which bear similarities to the cuprates, have also been found to host the unconventional SC. Our recent observation of SC at 6.1 K in correlated electron material K2Cr3As3 represents an obviously different paradigm, primarily because of its quasi-one-dimensional ( The revolutionary discovery of high-temperature SC in cuprates in the 1980s [1] has inspired the unprecedented enthusiasm to explore new superconductors, especially in transition-metal compounds. The continuous efforts over a quarter century have led to the discoveries of unconventional SC in a few classes of materials including iron pnictides [2], which bear two fundamental similarities to the cuprates -strong electron correlations and quasi two dimensionality. It is of great interest to explore possible unconventional SC in a Q1D material with significant electron correlations.Our recent observation of SC at T c = 6.1 K in K 2 Cr 3 As 3 realized the above possibility [3]. Unconventional SC was preliminarily evidenced by the peculiar properties including linear temperature dependence of resistivity in the normal state and extremely high upper critical field exceeding the Pauli limit by a factor of four [3] [7][8][9][10][11] in the normal state is evidenced by the NQR measurements [6]. So far, all the investigations [3-6] consistently point to the unconventional SC in the Q1D Crbased material.It is known that Peierls transition easily occurs in Q1D metallic systems [11,12], which prevents the appearance of SC [13]. The interchain coupling serves as a crucial control parameter, thus it is of interest to explore other possible analogues with varying interchain coupling strength. By the replacement of K + with Rb +