2023
DOI: 10.1002/tcr.202300103
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Remote Electronic Tuning of Chiral N‐Heterocyclic Carbenes

Abstract: Our recent efforts to develop novel N‐Heterocyclic carbene (NHC)‐catalyzed asymmetric reactions are described. During our investigation for development of the acylation reactions via acylazoliums generated by the reactions of NHCs and α‐oxidized aldehydes, we have observed significant effects of substitution at a remote site of the carbene carbon of NHCs. In addition, we also observed a significant enhancement of the enantioselectivity by the addition of carboxylate anions. From this observation, we proposed a… Show more

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