Drying behaviors of brown coal are
affected by internal water diffusion,
which is controlled by pore structures. To diminish the effect of
functional groups on drying, drying behaviors and pore structures
of only one kind of coal dried at different heating rates and atmospheres
were investigated. The final drying temperature was kept constant.
The relationships between pore structures, including specific surface
area (S
BET), volume of mesopores (V
meso), volume of macropores (V
macro), volume of total pores (V
total), and two fractal dimensions (D
I and D
II), and drying characteristics,
including maximum drying rate (v
max),
activation energy of drying surface water (E
1), activation energy of drying pore water (E
2), apparent diffusion coefficient surface water (D
eff‑1), and apparent diffusion coefficient
pore water (D
eff‑2), were correlated.
The relationship between basic pore parameters and fractal dimensions
was examined. For coals dried in N2, the S
BET was confirmed as one of the key factors influencing D
I. The v
max increased
with heating rates, resulting from the higher temperature at the same
drying time and larger S
BET and V
macro. The E
1 was
higher at faster heating rates, because of the higher temperature
gradient and the bigger D
I. The E
2 increased as heating rates increased from
3 to 20 °C/min and then decreased for flash drying (directly
dried at 200 °C). The increase could be also due to the higher
temperature gradient at higher heating rates. The decrease could be
because of the effect of V
macro on D
eff‑2. For coals dried in different atmospheres,
the higher E
1 and E
2 in air were due to oxidation reaction. The relatively large
heat conductivity of N2 led to the lower E
1. The small molecular diameter of CO2 led
to the lower E
2. There was no consistent
relationship between S
BET and D
I and between pore structures and drying characteristics
for coals dried in different atmospheres.