Removal of Banana Tree Fungi Using Green Tuff Rock Powder Waste Containing Zeolite

Abstract

Hinai green tuff, which is found in Akita Prefecture, Japan, is used for the production of building materials, etc. About 60% of all stone is emitted as waste powder and therefore it is important to find ways for recycling it. In this work, the characteristics of green tuff powder have been investigated. The results of scanning electron microscope (SEM) and elemental map observations indicate that the green tuff contains TiO2 on zeolite. The green tuff can therefore be used as a natural catalyst for producing hydrogen peroxide with moisture and oxygen with light. The optimum calcined temperature of the green tuff powder is about 800 °C, producing the hydroxyl radical from hydrogen peroxide decomposition without ultraviolet light (UV) and decomposition of the superoxide anion. As the application of green tuff powder, Cavendish banana trees found in the Philippines infected by a new Panama disease were treated with powder suspension in order to remove the fungus (a type of Fusarium wilt) due to the photocatalyst characteristics of powder. The suspension, prepared by using the powder was sprayed on the infected banana trees for about one month. Photograph observation indicated that the so-called 800 °C suspension spray was more effective in growing the infected banana trees.

Synthesis and Application of Zeolite Catalysts

“…Synthesis research on the MFI zeolite was also considered in this Special Issue, in which the effect of ethanol on the morphology and textural properties was deeply investigated [17]. A method to obtain naturally occurring TiO 2 on zeolite composite from green tuff was developed, which could be used as a natural photocatalyst [18]. In addition, two review articles focusing special attention on the synthesis of hierarchical zeolites and catalytic advances were reported [19,20].…”