“…It was estimated that around 15% of dye was lost during dyeing process and eventually discharged into environment, 1 exerting heavy pressure on environmental protection and sustainability. [2][3][4][5] The dyeing effluents are colored even in a very low concentration. This necessitates to degrade the dyes in effluents, at least to decolorize them before effluent disposal to environment.…”
Section: Introductionmentioning
confidence: 99%
“…TiO 2 , Fe 3 O 4 ), 1,2,18,25,26,30 and by using highfrequency ultrasonic atomizer. 3 However, the addition of chemical reagent increases the cost and 4 possibly causes secondary pollution associated with the chemicals. 29 When nonmagnetic catalysts ( e.g.…”
Section: Introductionmentioning
confidence: 99%
“…4,[21][22][23][24][25] To improve decolorization rate of the dye, combinational techniques are universally adopted involving two or three kinds of AOPs. [1][2][3][4][18][19][20][21][22][23][24][25][26][27][28][29][30] The documented references related to AOPs are focused on increasing the concentration of radicals by adding chemical oxidants (e.g. O 3 , H 2 O 2 , K 2 Cr 2 O 7 ), 2,19,20,29 Fenton's reagent, 4,[21][22][23][24][25] radical-producer (e.g.…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3][4][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31] An advanced oxidation process has been defined as a process that involves formation and subsequent reactions related to highly reactive free radicals, such as ·OH, ·O 2 -, ·O 2 H, which are capable of oxidizing dyes to render decolorized effluents. 2,19 The decolorization of dyes in an AOP process has two meanings, i.e., partial degradation to form aromatic intermediates and deep mineralization to generate oxyacids, CO 2 , and H 2 O.…”
Section: Introductionmentioning
confidence: 99%
“…O 3 , H 2 O 2 , K 2 Cr 2 O 7 ), 2,19,20,29 Fenton's reagent, 4,[21][22][23][24][25] radical-producer (e.g. CCl 4 ), 3,4,28,29 and catalyst (e.g. TiO 2 , Fe 3 O 4 ), 1,2,18,25,26,30 and by using highfrequency ultrasonic atomizer.…”
An ultrasound-assisted advanced oxidation process (AOP) has been demonstrated for sonocatalytic degradation of methyl orange (MO) with Fe 3 O 4 /polyaniline (Fe 3 O 4 /PANI) microspheres in near neutral solution (pH ~6). The Fe 3 O 4 /PANI microspheres were characterized with XRD, SEM, TEM, FT-IR, XPS, and zeta-potential measurements, and further tested in the role of adsorption and sonocatalytic decolorization of MO in solution. The isotherms and kinetics of MO adsorption with Fe 3 O 4 /PANI follow the Langmuir model and the pseudo-second-order model, respectively. The kinetics of sonocatalytic decolorization of MO with Fe 3 O 4 /PANI conforms to a combinational model involving the pseudo-second-order adsorption model and the pseudo-first-order degradation model, since Fe 3 O 4 /PANI has a high capacity to adsorb MO in solution. The percentage of room-temperature sonocatalytic degradation of MO with Fe 3 O 4 /PANI is about 4.8, 8.8, and 5.7 times of that with Fe 3 O 4 , dedoped Fe 3 O 4 /PANI, and ultrasonication alone, respectively. The eco-friendly Fe 3 O 4 /PANI featured with superparamagnetism and excellent reusability offers a promising sonocatalyst for rapid decolorization and enhanced degradation of azodyes in effluents.
“…It was estimated that around 15% of dye was lost during dyeing process and eventually discharged into environment, 1 exerting heavy pressure on environmental protection and sustainability. [2][3][4][5] The dyeing effluents are colored even in a very low concentration. This necessitates to degrade the dyes in effluents, at least to decolorize them before effluent disposal to environment.…”
Section: Introductionmentioning
confidence: 99%
“…TiO 2 , Fe 3 O 4 ), 1,2,18,25,26,30 and by using highfrequency ultrasonic atomizer. 3 However, the addition of chemical reagent increases the cost and 4 possibly causes secondary pollution associated with the chemicals. 29 When nonmagnetic catalysts ( e.g.…”
Section: Introductionmentioning
confidence: 99%
“…4,[21][22][23][24][25] To improve decolorization rate of the dye, combinational techniques are universally adopted involving two or three kinds of AOPs. [1][2][3][4][18][19][20][21][22][23][24][25][26][27][28][29][30] The documented references related to AOPs are focused on increasing the concentration of radicals by adding chemical oxidants (e.g. O 3 , H 2 O 2 , K 2 Cr 2 O 7 ), 2,19,20,29 Fenton's reagent, 4,[21][22][23][24][25] radical-producer (e.g.…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3][4][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31] An advanced oxidation process has been defined as a process that involves formation and subsequent reactions related to highly reactive free radicals, such as ·OH, ·O 2 -, ·O 2 H, which are capable of oxidizing dyes to render decolorized effluents. 2,19 The decolorization of dyes in an AOP process has two meanings, i.e., partial degradation to form aromatic intermediates and deep mineralization to generate oxyacids, CO 2 , and H 2 O.…”
Section: Introductionmentioning
confidence: 99%
“…O 3 , H 2 O 2 , K 2 Cr 2 O 7 ), 2,19,20,29 Fenton's reagent, 4,[21][22][23][24][25] radical-producer (e.g. CCl 4 ), 3,4,28,29 and catalyst (e.g. TiO 2 , Fe 3 O 4 ), 1,2,18,25,26,30 and by using highfrequency ultrasonic atomizer.…”
An ultrasound-assisted advanced oxidation process (AOP) has been demonstrated for sonocatalytic degradation of methyl orange (MO) with Fe 3 O 4 /polyaniline (Fe 3 O 4 /PANI) microspheres in near neutral solution (pH ~6). The Fe 3 O 4 /PANI microspheres were characterized with XRD, SEM, TEM, FT-IR, XPS, and zeta-potential measurements, and further tested in the role of adsorption and sonocatalytic decolorization of MO in solution. The isotherms and kinetics of MO adsorption with Fe 3 O 4 /PANI follow the Langmuir model and the pseudo-second-order model, respectively. The kinetics of sonocatalytic decolorization of MO with Fe 3 O 4 /PANI conforms to a combinational model involving the pseudo-second-order adsorption model and the pseudo-first-order degradation model, since Fe 3 O 4 /PANI has a high capacity to adsorb MO in solution. The percentage of room-temperature sonocatalytic degradation of MO with Fe 3 O 4 /PANI is about 4.8, 8.8, and 5.7 times of that with Fe 3 O 4 , dedoped Fe 3 O 4 /PANI, and ultrasonication alone, respectively. The eco-friendly Fe 3 O 4 /PANI featured with superparamagnetism and excellent reusability offers a promising sonocatalyst for rapid decolorization and enhanced degradation of azodyes in effluents.
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