1The emergence of the spontaneous polarization in the hexagonal RMnO 3 system (R = Sc, Y, In, Dy -Lu) is one of the singular properties and, at the same time, one of the greatest mysteries of this class of compounds. Taking YMnO 3 as reference compound for the series (see Methods), Curie temperatures inexplicably spreading from 910 K to 1250 K have been reported 10-16, 18, 19 . In some of these cases ferroelectricity has been claimed to emerge together with a trimerizing lattice distortion in a single-step transition 16,18,19 . In other cases these two features have been proposed to occur separately [10][11][12][13][14][15] . On the theoretical side, the two-transition scenario has initially been supported by density-functional-theory calculations 20 . A more detailed analysis, however, suggests improper ferroelectricity triggered by the lattice trimerization in a single-step transition 21,22 , in which secondary anomalies are yet possible due to the breaking of residual symmetries 23 . Direct measurement of the spontaneous polarization as function of temperature would clarify this puzzling situation. This was done once in a pyrocurrent measurement which pointed to an onset of ferroelectricity at 933 K 16 . All attempts to reproduce this experiment failed, however. Thus, in spite of 50 years of research, the emergence of the polar order in the hexagonal RMnO 3 multiferroics is surrounded by contradictions. This uncertainty extends to the universality class of this ferroelectric transition, as this basic question depends on the precise nature of the state undergoing the polar instability. The universality class and the corresponding critical behavior determines important physical properties from the macro-to the nanoscale. Understanding such functionalities is infinitely more difficult if the emergence of the ferroelectric order itself is unclear. Thus, for putting the intense research on the unusual properties of ferroelectric order in the hexagonal RMnO 3 system 2, 3, 5,8,9 onto a solid basis, this situation must be resolved.
2Here we present nonlinear optical experiments in which the electromagnetic field of a frequency-doubled light wave couples directly and linearly to the spontaneous polarization of YMnO 3 .They reveal a polarization emerging at T C 1259 K with a subdued increase in amplitude showing no anomalies or discontinuities. Piezoresponse force microscopy (PFM) confirms that the ferroelectric domain pattern is seeded right below T C . Monte-Carlo simulations reveal how topologically created vortex-like defects in the MnO 5 tilt pattern determine the ferroelectric state and many of its unusual properties. In particular, we show that the "second transition" below T C is not associated to a phase transition, but caused by a finite-size scaling effect.At room temperature, the spontaneous polarization P s = 5.6 µC/cm 2 of YMnO 3 is observed together with unit-cell-trimerizing tilts of the MnO 5 bipyramids and Y displacements along the c axis. The tilt is parameterized 22, 23 by the observable amplitude ...