2020
DOI: 10.1088/1361-648x/ab60e3
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Reorientation of Eu2+-cation vacancy dipolar complex in KCl/KBr binary crystals

Abstract: In this work we describe the polarization and depolarization process of Eu 2+ -V C dipoles in Eu 2+ doped solid solutions of KCl and KBr considering in detail the different jumping paths of the cation vacancy within individual arrangements of minority anions on the first two anion shells surrounding the dipolar complex. Experimental depolarization curves of binary crystals show in contrast to the single depolarization peak in unitary crystals, up to at least two additional depolarization peaks. These two addit… Show more

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