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The polymer cold spray (CS) process has recently been demonstrated as a promising coating and repair technique for fiber-reinforced polymer composites (FRPs). However, a noticeable variation in coating thickness (herein referred to as checkerboard pattern) often occurs in the initial pass of low-pressure CS deposition. The checkerboard pattern occurs due to the periodic variations in matrix thickness and volume above the subsurface fiber weave pattern. When the initial pass exhibits the so-called checkerboard pattern, the CS deposition for subsequent passes may be negatively affected in terms of deposition efficiency, porosity, adhesion, surface roughness, and thickness consistency. The present work compares results of both numerical simulations and experimental studies performed to reveal the governing mechanisms for and elimination of checkerboarding. Single particle impact numerical simulations are conducted to observe thermomechanical behavior of particles during CS impact on the FRP surface at different regions of the composite material. Complementary experimental CS studies of exemplar powders onto FRPs with various surface interlayer thicknesses are also presented and discussed. Experimental analyses of deposits include microstructural observations to compare against the simulations while also providing practical strategies for the elimination of checkerboarding effects. It is demonstrated that the thickness and volume of the matrix region underneath the impact area are the main contributing factors that govern the CS deposition variations on CFRP substrates. As such, increasing the surface epoxy layer thickness beyond a critical value can reduce the effect of substrate stiffness effects imposed by the subsurface fiber tows, thereby effectively eliminating the checkerboard patterns.
The polymer cold spray (CS) process has recently been demonstrated as a promising coating and repair technique for fiber-reinforced polymer composites (FRPs). However, a noticeable variation in coating thickness (herein referred to as checkerboard pattern) often occurs in the initial pass of low-pressure CS deposition. The checkerboard pattern occurs due to the periodic variations in matrix thickness and volume above the subsurface fiber weave pattern. When the initial pass exhibits the so-called checkerboard pattern, the CS deposition for subsequent passes may be negatively affected in terms of deposition efficiency, porosity, adhesion, surface roughness, and thickness consistency. The present work compares results of both numerical simulations and experimental studies performed to reveal the governing mechanisms for and elimination of checkerboarding. Single particle impact numerical simulations are conducted to observe thermomechanical behavior of particles during CS impact on the FRP surface at different regions of the composite material. Complementary experimental CS studies of exemplar powders onto FRPs with various surface interlayer thicknesses are also presented and discussed. Experimental analyses of deposits include microstructural observations to compare against the simulations while also providing practical strategies for the elimination of checkerboarding effects. It is demonstrated that the thickness and volume of the matrix region underneath the impact area are the main contributing factors that govern the CS deposition variations on CFRP substrates. As such, increasing the surface epoxy layer thickness beyond a critical value can reduce the effect of substrate stiffness effects imposed by the subsurface fiber tows, thereby effectively eliminating the checkerboard patterns.
This study focuses on the successful fabrication of three distinct types of CoCrFeNi high entropy alloy (HEA) coatings through cold spray (CS) technology, with an emphasis on analyzing the impact of varying crucial CS parameters (spraying temperature and the range of powder particle size), on the coating's microstructure and tribological properties. Contrasted with conventional thermal spraying techniques, lower operational temperature in CS safeguards the materials from undergoing oxidation or phase transitions that are typically induced by high-temperature conditions. Additionally, the high-velocity impact of particles onto the substrate within CS process triggers plastic deformation, resulting in the creation of coatings that are characterized by heightened hardness, and greater density. Such coatings exhibit significantly enhanced performance and durability. The cocktail effect observed in CoCrFeNi HEA is reflected in a suite of exceptional properties that markedly surpass those exhibited by traditional alloys. Chiefly, this phenomenon is manifested through the alloy's exceptionally high hardness and dense structure, positioning CoCrFeNi HEA as a promising candidate for applications in high-wear scenarios. Experimental outcomes indicate that when smaller powder particles and higher spraying temperatures are employed, the porosity of CSed CoCrFeNi HEA coatings was observed to decrease by nearly an order of magnitude, concomitant with a 22.46% enhancement in microhardness. This improvement in microhardness translates into a significant reduction of over 72% in the wear rate, underscoring the positive correlation between enhanced microstructural integrity and wear resistance properties. By meticulously tuning spraying temperature and powder particle size, the resulting microstructure can be rendered increasingly dense and refined.
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