The aim of this article is to study the Bloch-Kato exponential map and the Perrin-Riou big exponential map purely in terms of (ϕ, Γ )-modules over the Robba ring. We first generalize the definition of the Bloch-Kato exponential map for all the (ϕ, Γ )-modules without using Fontaine's rings B crys , B dR of p-adic periods, and then generalize the construction of the Perrin-Riou big exponential map for all the de Rham (ϕ, Γ )-modules and prove that this map interpolates our Bloch-Kato exponential map and the dual exponential map. Finally, we prove a theorem concerning the determinant of our big exponential map, which is a generalization of theorem δ(V) of Perrin-Riou. The key ingredients for our study are Pottharst's theory of the analytic Iwasawa cohomology and Berger's construction of p-adic differential equations associated to de Rham (ϕ, Γ )-modules.