We study infinite weighted graphs with view to \textquotedblleft limits at
infinity,\textquotedblright or boundaries at infinity. Examples of such
weighted graphs arise in infinite (in practice, that means \textquotedblleft
very\textquotedblright large) networks of resistors, or in statistical
mechanics models for classical or quantum systems. But more generally our
analysis includes reproducing kernel Hilbert spaces and associated operators on
them. If $X$ is some infinite set of vertices or nodes, in applications the
essential ingredient going into the definition is a reproducing kernel Hilbert
space; it measures the differences of functions on $X$ evaluated on pairs of
points in $X$. And the Hilbert norm-squared in $\mathcal{H}(X)$ will represent
a suitable measure of energy. Associated unbounded operators will define a
notion or dissipation, it can be a graph Laplacian, or a more abstract
unbounded Hermitian operator defined from the reproducing kernel Hilbert space
under study. We prove that there are two closed subspaces in reproducing kernel
Hilbert space $\mathcal{H}(X)$ which measure quantitative notions of limits at
infinity in $X$, one generalizes finite-energy harmonic functions in
$\mathcal{H}(X)$, and the other a deficiency index of a natural operator in
$\mathcal{H}(X)$ associated directly with the diffusion. We establish these
results in the abstract, and we offer examples and applications. Our results
are related to, but different from, potential theoretic notions of
\textquotedblleft boundaries\textquotedblright in more standard random walk
models. Comparisons are made.Comment: 38 pages, 4 tables, 3 figure