Investigation that Elevated levels of static electricity build-up on the surfaces of work clothes, different technological structures, and polymeric materials can cause disruptions to the techno-bio system, resulting in adverse physiological effects in humans, accidents caused by humans, and environmental disasters. Under conditions of low temperatures, electrostatic charge on polymeric materials is intensively generated. Synthetic materials have an increased ability to electrify. The processes were studied the mechanisms of the occurrence of a electricity an polymer materials of clothing in winter. The logical structure of the model of the formation of an electrostatic field on the surface of polymer materials of objects in environmental conditions during a snowstorm has been developed. A set of materials for experimental thermal protective clothing was investigated. The findings from the investigation into the process of electrification in the layers of materials used to make thermally protective clothing are gathered and given. As follows from the graphs, the limiting value of the electrostatic field strength can occur already with an external field of 15000 V/m. The formation of charges is facilitated by the physical conditions of the snowstorm electrification in the system of polymer structures.