When the well bottom temperature rises owing to increased
well
depth and formation complexity, the inadequacies of naturally modified
polymeric fluid loss agents were revealed one by one, and synthetic
polymeric fluid loss agents emerged as the essential technology to
handle these problems. Nanomaterials were gradually being employed
to increase the performance of polymeric fluid loss agents. Through
free radical polymerization of amide polymers with silica nanoparticles
in aqueous solution, a novel nano-graft copolymer (AAN-g-SiO2) was prepared for usage as a water-based drilling fluid loss agent.
Fourier transform infrared spectroscopy and thermogravimetric analyses
were used to investigate the structural characteristics and thermal
stability of the polymer chains. Then, 4% bentonite freshwater-based
mud and different concentrations of NaCl/CaCl2-based mud
were prepared and added to the fluid loss agent AAN-g-SiO2. Moreover, high-temperature aging was carried out, and the API filtration
volume of base mud and rheological characteristics were assessed.
The fluid loss agent was demonstrated to withstand a high temperature
of 220 °C, with the freshwater-based mud filtration volume at
this temperature being 13.25 mL. Also, at 180 °C, AAN-g-SiO2 could be resistant to calcium and salt. Finally, we addressed
the mechanism of AAN-g-SiO2 filtration using scanning electron
microscopy and zeta potential distribution. The results showed that
the inclusion of AAN-g-SiO2 may increase the stability
of the drilling fluid system, resulting in the production of a thin
and dense filter cake with no folds or pores visible at the microscopic
level.