The gel-based sensors have developed rapidly in recent
years toward
multifunctionality. However, there are still some challenges that
need to be solved, such as poor mechanical properties and inaccessibility
to wet or water environments. To address these issues, we have developed
an ionogel with a semi-interpenetrating network structure by adopting
poly(vinylidene fluoride-co-hexafluoropropylene)
as the linear non-cross-linked network, a double-bonded ionic liquid
and double-bonded capped polyurethane as the cross-linked network,
and an ionic liquid as the conductive media. The obtained ionogel
exhibits tunable mechanical properties (3.67–8.76 MPa) and
excellent sensing properties (IG-20, GF = 8.2). The superb environmental
stability and self-healing properties of the ionogel were also demonstrated.
Meanwhile, adhesion, self-healing, and sensing performance were guaranteed
for underwater due to the presence of a large number of C–F
bonds. We strongly believe that this ionogel with excellent mechanical
properties and underwater communication is expected for monitoring
the health of the human body and information transmission in the future.