After two centuries of the discovery, we now know that there are several types of bauxites, in which mineralogy points to the most appropriate application. In the non-metallurgical industry, bauxites with refractory grades have been applied as raw materials in the production of high-alumina refractories for both shaped and unshaped. The increase in the cost of other sources of high-alumina raw materials has encouraged the refractory producers to find a more cost-effective substitute, such as refractory-grade calcined bauxites (RGB). Nowadays, concerns rise regarding the availability of RGB due to the continuous restrictions taking place in China, which has a 95% market share. This work presents a new RGB of high-alumina content (~85%) from a Brazilian source in which process enabled a technology with high refractoriness.